Hydrogenated castor oilCAS:8001-78-3

Appearance and Properties: Presents as a transparent viscous liquid, with color ranging from nearly colorless to pale yellow and excellent clarity.


Sensory Characteristics: Possesses a subtle aroma, with a mild and slightly pungent flavor profile.


Solubility: Highly soluble in ethanol, and only partially miscible with aliphatic hydrocarbon solvents.


Room Temperature Stability: Maintains a stable liquid state under standard ambient storage conditions, without phase separation.


Product Details

1. Product Overview


Hydrogenated Castor Oil (HCO), a naturally sourced waxy solid, is manufactured via the catalytic hydrogenation of castor oil—an extraction from the seeds of the castor bean plant (Ricinus communis) . Its chemical composition is dominated by 12-hydroxystearic acid triglycerides, formed through the saturation of unsaturated double bonds in ricinoleic acid, the primary fatty acid in raw castor oil . Physically, HCO presents as a white to pale yellow waxy solid, flake-like particles, or fine powder, with a consistent, inert appearance .

Classified as a multifunctional organic wax and rheology modifier, HCO retains the unique hydroxyl (-OH) functional groups inherent to castor oil while gaining enhanced thermal stability and a significantly elevated melting point through hydrogenation. This synergistic combination of natural origin and modified properties positions it as a staple ingredient across diverse industrial sectors, including cosmetics and personal care, pharmaceuticals, coatings and inks, plastics manufacturing, and lubricant production . As a bio-based chemical with renewable origins, HCO aligns with modern sustainability goals, serving as an indispensable natural additive in high-performance formulations due to its exceptional thickening, gelling, film-forming, and lubricating capabilities .


Hydrogenated castor oilCAS:8001-78-3


2. Key Features

  • Natural & Renewable Provenance: Derived entirely from the castor plant, HCO boasts a Renewable Carbon Index (RCI) exceeding 95% , making it a cornerstone of green chemistry initiatives and sustainable manufacturing practices .

  • Enhanced Melting Point & Thermal Resilience: Hydrogenation elevates its melting point to 85–88°C—markedly higher than the liquid state of unmodified castor oil—rendering it solid at ambient temperatures and ideal for heat-stable formulations .

  • Superior Thickening & Gelling Performance: When melted in the oil phase and cooled, HCO forms a three-dimensional network structure that substantially increases formulation viscosity and consistency. This property is critical for imparting desirable texture and long-term stability to creams, solid sticks (e.g., lipsticks, deodorant sticks), and semi-solid ointments .

  • Exceptional Film-Forming & Water-Resistant Traits: Upon application, HCO forms a smooth, glossy film with robust water resistance and moisturizing benefits, making it a favored component in coatings, leather care products, and skincare formulations .

  • High Safety & Regulatory Compliance: Approved by the FDA for use in food contact materials, HCO and its derivatives (e.g., PEGylated variants) have been deemed safe for intended use by the Cosmetic Ingredient Review (CIR) panel . It also meets the stringent standards of the United States Pharmacopeia/National Formulary (USP/NF) for pharmaceutical applications .

  • Multifunctional Additive Capabilities: Acts as an anti-caking agent in powders to improve flowability and release properties; functions as a lubricant and mold release agent in plastics processing; and serves as a thickener in the production of lubricating greases .

    Hydrogenated castor oilCAS:8001-78-3


    3. Technical Specifications with Explanations

    Based on USP29-NF24 and relevant industrial standards, the key technical parameters of HCO are outlined below:


    Parameter
    Typical Value/Specification
    Description & Significance
    CAS Number
    8001-78-3 (Hydrogenated Castor Oil); 8031-45-6 (sulfonated derivatives)
    Universal chemical identifiers for material traceability and regulatory compliance.
    Primary Component
    Glyceryl tri-12-hydroxystearate
    The core functional constituent post-hydrogenation, responsible for HCO’s waxy nature and high melting point.
    Appearance
    White to pale yellow powder, flakes, or waxy solid
    A visual quality benchmark; different physical forms are tailored to specific processing requirements (e.g., melting vs. dry blending).
    Melting Point
    85–88°C
    A defining specification: HCO remains solid below this temperature and liquefies above, critical for its role as a structuring agent and thermal stability in formulations.
    Hydroxyl Value
    154–162 mg KOH/g
    A key functional metric measuring hydroxyl group content, directly influencing reactivity (e.g., with isocyanates) and compatibility in polar systems.
    Iodine Value
    ≤ 5
    A primary purity indicator reflecting the degree of unsaturation; low values confirm complete hydrogenation, ensuring chemical stability and resistance to oxidation.
    Saponification Value
    176–182 mg KOH/g
    Indicates the average molecular weight of triglycerides, used to verify product purity and batch consistency.
    Free Fatty Acids
    ≤ 1.1 mL (0.1 N NaOH/20g)
    Controls residual free fatty acid content; low levels prevent rancidity, ensuring product stability and odor neutrality.
    Density
    ~0.99 g/cm³ (25°C)
    Slightly less dense than water, used for volume-to-weight conversions in formulation scaling.
    Particle Size (D50)
    8.0–12.0 μm (micronized grade)
    Particle size distribution for micronized variants, impacting dispersion in coatings/powders and final tactile performance.
    Biodegradability
    Complies with OECD 301 standards
    Demonstrates ready biodegradability under specified conditions, ensuring environmental compatibility.

    4. Applications

    Cosmetics & Personal Care

    • Color Cosmetics: Acts as a core structuring agent and thickener in lipsticks, lip balms, foundation sticks, eye shadow sticks, and mascaras, enhancing moldability, thermal stability, and smooth application while ensuring uniform pigment dispersion .

    • Skin Care Products: Functions as a viscosity modifier, film former, and emollient in creams, sunscreens, and body lotions, improving texture, delivering a silky skin feel, and forming a protective barrier that boosts water resistance .

    • Hair Care: Provides hold and luster in styling products such as hair waxes and pomades.

    • Other Uses: Serves as a pigment dispersant, ensuring even distribution of colorants in the oil phase of formulations.

    Pharmaceutical & Veterinary

    • Pharmaceutical Excipient: Utilized as a tablet lubricant and sustained-release matrix material in oral solid dosage forms. Its high melting point enables integration into hot-melt extrusion processes .

    • Long-Acting Injectables: In veterinary medicine, combined with hydrophobic carriers to develop long-acting injectable formulations, extending drug release for prolonged therapeutic effects .

    • Ointment Base: Acts as an oil phase component in semi-solid pharmaceutical preparations, supporting formulation stability and drug delivery.

    Plastics & Polymer Industry

    • Plastic Lubricant & Mold Release Agent: In the processing of PVC, polyolefins, and other polymers, acts as both internal and external lubricant, enhancing melt flow, preventing melt fracture, and facilitating easy mold release .

    • Bioplastics: Serves as a processing aid and modifier for bio-based plastics, improving processability and flexibility.

    Coatings & Inks

    • Coating Additive: In water-based and solvent-based coatings, functions as a rheology modifier, anti-settling agent, and matting agent, enhancing storage stability and application performance .

    • Printing Inks: Acts as a thickener and gelling agent, regulating rheology and thixotropy to improve print clarity and consistency.

    • Powder Coatings: Serves as a flow aid and anti-caking agent, preventing particle agglomeration and boosting spray efficiency.

    Lubricating Greases & Industrial Oils

    • Grease Thickener: Reacts with metal hydroxides (e.g., lithium, calcium) to form 12-hydroxystearate soaps—the primary raw material for high-performance general-purpose greases (e.g., lithium-based greases) .

    • Metalworking Fluids: Used as a lubricity and anti-corrosion additive, enhancing tool life and workpiece quality.

    Agriculture & Fertilizers

    • Fertilizer Anti-Caking Agent: Acts as a coating or anti-caking agent for granular fertilizers, preventing moisture absorption and caking during storage and transportation, and maintaining granule flowability .

    • Seed Coating: Serves as a binder and controlled-release agent in seed treatment formulations, promoting adhesion of active ingredients to seeds while providing moderate water resistance.

    Food & Food Contact Applications

    • Food Contact Materials: FDA-approved for use in paper, paperboard, and polymer materials intended for food contact, either as an additive or coating. Its sulfonated derivatives are also utilized in food contact paper manufacturing .

    • Food Additive: Permitted for use as an anti-caking or surface treatment agent in select regions, subject to local regulatory requirements.

    5. Product Grade Comparison

    Parameter/Grade
    Industrial Grade (Flakes/Solid)
    Micronized Grade (Powder)
    Pharmaceutical Grade (USP/NF)
    Cosmetic Grade
    Core Standard
    General industrial specifications
    Specific particle size requirements
    Meets USP/NF pharmacopeial standards
    Complies with cosmetic ingredient specifications
    Physical Form
    Flakes, blocks, granules
    White fine powder
    Flakes or powder
    Flakes, powder, or granules
    Melting Point
    85–88°C
    85–88°C
    85–88°C
    85–88°C
    Particle Size (D50)
    Not applicable
    8.0–12.0 μm (max )
    Not applicable
    Customizable based on formulation needs
    Critical Parameters
    Melting point, acid value, iodine value, saponification value
    Particle size distribution, bulk density, flowability
    Heavy metals, microbial limits, purity
    Color, odor, heavy metal content
    Primary Applications
    Grease manufacturing, plastics processing, rubber, industrial coatings
    Powder coatings, fertilizer anti-caking, seed coating, premium inks
    Oral solid dosage forms, long-acting injections, pharmaceutical excipients
    Lipsticks, foundations, skincare products, hair waxes
    Typical Suppliers
    Acme Hardesty Co., et al.
    Micro Powders (NATUREFINE H325), et al.
    Merck, BASF, et al.
    Croda, Ashland, et al.
    Certifications/Sustainability
    Standard industrial certifications
    Renewable Carbon Index >95%, biodegradable certification
    USP/NF compliance, GMP certification
    Sustainable castor oil certifications, natural/organic compliance

    6. Purchasing & Selection Guide

    Select by Physical Form

    • Flakes/Blocks/Solid:

      • Advantages: Cost-effective, convenient for packaging and transportation, ideal for large-scale melting processes.

      • Disadvantages: Challenging to disperse uniformly when added directly to powder mixtures.

      • Suitable for: Grease production, plastics processing, formulations requiring oil-phase heating.

    • Micronized Powder:

      • Advantages: Fine particle size (5–15 μm) enables room-temperature dry blending with other powders, ensuring excellent dispersion, smooth tactile feel, and glossy finish .

      • Disadvantages: Higher processing costs; increased surface area increases moisture absorption risk.

      • Suitable for: Powder coatings, fertilizer anti-caking, seed coating, premium cosmetic powders, dry-blend formulations.

    Select by Purity & Application Standard

    • Industrial Grade: A cost-effective option for greases, plastics, and industrial coatings where strict purity requirements are not mandatory.

    • Cosmetic Grade: Mandatory for cosmetic formulations. Prioritize whiteness, odor (odorless or faint characteristic scent), and heavy metal content to ensure compatibility with sensory quality and safety standards .

    • Pharmaceutical Grade (USP/NF): Essential for oral solid dosage forms and sustained-release materials. Must meet pharmacopeial standards—request Drug Master File (DMF) and current Good Manufacturing Practices (cGMP) compliance documentation from suppliers .

    Key Performance Indicator Verification

    • Melting Point (85–88°C): Ensures structuring capability and thermal stability in end products.

    • Hydroxyl Value (154–162): Critical for chemical reactions (e.g., lithium grease synthesis, polyurethane production) as it dictates formulation stoichiometry.

    • Iodine Value (≤5): A key marker of oxidative stability and hydrogenation completeness—lower values indicate superior stability and aging resistance.

    • Particle Size Distribution: For micronized grades, verify that D50 and maximum particle size align with application requirements (e.g., spray coating processes).

    7. Frequently Asked Questions (FAQ)

    Q: What distinguishes hydrogenated castor oil from regular castor oil?
    A: Regular castor oil is a liquid vegetable oil primarily composed of ricinoleic acid (with unsaturated double bonds). Hydrogenated castor oil is produced via hydrogenation, which saturates these unsaturated bonds, converting the liquid oil into a solid waxy material . This process increases melting point and oxidation resistance, endowing HCO with thickening and film-forming properties absent in raw castor oil.
    Q: What role does hydrogenated castor oil play in lipstick formulations?
    A: It serves as a critical structural component. As a thickener and gelling agent, it elevates the melting point and hardness of lipsticks, preventing deformation or melting in warm environments. Additionally, it facilitates uniform pigment dispersion, enhances smooth application, and imparts a desirable gloss .
    Q: Is hydrogenated castor oil biodegradable?
    A: Yes. As a plant-derived natural derivative, HCO is classified as readily biodegradable and meets the OECD 301 biodegradability testing standards .
    Q: How can hydrogenated castor oil be incorporated into formulations?
    A: Due to its high melting point (85–88°C), HCO must be integrated via heating:
    • Oil Phase Addition: Combine with oil-phase ingredients and heat to 90–95°C until fully melted and dissolved, then proceed with emulsification or mixing.

    • Note: HCO cannot be dissolved in cold water or room-temperature oils, as it will remain as solid particles and fail to deliver thickening or structuring effects.

    Q: What storage conditions are required for hydrogenated castor oil?
    A: Store in sealed containers in a cool, dry, well-ventilated area, protected from direct sunlight and strong oxidizing agents . Micronized grades, with their larger surface area, are more susceptible to moisture absorption and require enhanced sealing. Under proper storage, HCO typically has a shelf life of 2–3 years.
    Q: Can hydrogenated castor oil be used in vegan or natural cosmetics?

    A: Yes. HCO is 100% plant-derived, making it suitable for vegetarian and vegan formulations. Many suppliers offer sustainably certified castor oil-based HCO that meets natural and organic cosmetic standards .


    Hydrogenated castor oilCAS:8001-78-3


    8. Delivery, Certification & Service

    Delivery Capabilities

    • Inventory Status: Regular flakes and micronized grades are available from regional warehouses for timely fulfillment.

    • Sample Program: Small quantities (e.g., 500g) are provided for formulation testing and performance evaluation.

    • Packaging Options:

      • Industrial grade: 20 kg multi-ply paper/woven bags, 25 kg fiber drums.

      • Micronized grade: 15 kg or 20 kg fiber drums or paper bags with polyethylene liners.

      • Custom packaging: Available for bulk orders.

    • Shipping: Classified as a non-hazardous material; standard freight options include express, less-than-truckload (LTL), and full truckload shipping.

      8. Delivery, Certification & Service

      Delivery Capabilities

      • Inventory Status: Regular flakes and micronized grades are available from regional warehouses for timely fulfillment.

      • Sample Program: Small quantities (e.g., 500g) are provided for formulation testing and performance evaluation.

      • Packaging Options:

        • Industrial grade: 20 kg multi-ply paper/woven bags, 25 kg fiber drums.

        • Micronized grade: 15 kg or 20 kg fiber drums or paper bags with polyethylene liners.

        • Custom packaging: Available for bulk orders.

      • Shipping: Classified as a non-hazardous material; standard freight options include express, less-than-truckload (LTL), and full truckload shipping.


        Hydrogenated castor oilCAS:8001-78-3


        Quality Certifications & Compliance

        • Manufacturing Standards: Production facilities are ISO 9001:2015 certified, ensuring consistent quality management systems. Pharmaceutical Grade HCO is manufactured in compliance with current Good Manufacturing Practices (cGMP) to meet pharmacopeial requirements .

        • Batch Documentation: Each shipment is accompanied by a Certificate of Analysis (COA), which comprehensively documents key quality parameters including appearance, melting point, acid value, iodine value, saponification value, hydroxyl value, and particle size (for micronized grades) .

        • Safety Documentation: Safety Data Sheets (SDS/MSDS) are available in multiple languages to support global regulatory compliance and workplace safety.

        • Third-Party Validation: Independent test reports (e.g., from SGS) can be provided upon customer request, verifying product quality and compliance with specified standards.

        • Specialized Certifications: Additional compliance documents are available to meet diverse market requirements, including:

          • Non-GMO declaration (confirming no genetically modified castor oil sources)

          • Allergen statement (certifying absence of common allergens)

          • Halal certificate (for food, cosmetic, and pharmaceutical applications in Muslim-majority markets)

          • Kosher certificate (aligning with Jewish dietary and product standards)

          • Sustainable castor oil certification (validating environmentally responsible sourcing and production)

        Technical Support & Value-Added Services

        • Expert Technical Consultation: A dedicated team of application specialists offers online support for product selection, heating/dissolution process optimization, formulation adjustment (e.g., thickening efficiency, gelling performance), and process adaptation to ensure seamless integration into customer workflows .

        • Customized Solutions: For qualified long-term partners, tailored services are available, including customized particle size specifications, bespoke quality standards aligned with specific application needs, and personalized packaging solutions .

        • Regulatory Support: Comprehensive documentation packages are provided to facilitate product registration in target markets, streamlining compliance with local regulatory frameworks.

        Available Documentation

        To support customer operations, regulatory compliance, and product integration, the following documents are readily available upon request:
        • Certificate of Analysis (COA)

        • Safety Data Sheet (SDS/MSDS)

        • Technical Data Sheet (TDS)

        • Product Specification (PS)

        • Certificate of Origin (COO)

        • Halal certificate

        • Kosher certificate

        • Sustainable castor oil certification

        • Pharmaceutical excipient documentation (including Drug Master File (DMF), where applicable)


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